Small question, am I right in assuming that I can access the folders and open files from a MAC and a WINDOWS PC? So can I use a Windows PC and my wife a MAC at the same time to access the NAS? Thank you dear people :)

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Answer

Yes, it works perfectly with Mac, Windows and Linux.

Answer

I can't answer for MAC as I'm working with a Windows PC, but in my opinion this should work.
Have a look at SpaceRex, where you will find many instructive videos regarding Synology:

https://youtu.be/T1xW97eyXB8?si=3_CnLzg2NW2px3OK

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Question about Synology DS224+

Small question, am I right in assuming that I can access the folders and open files from a MAC and a WINDOWS PC? So can I use a Windows PC and my wife a MAC at the same time to access the NAS? Thank you dear people :)